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A palladium containing metal-organic framework (MOF) compound has been synthesized from MOF, (Zn4O)3(BDC–NH2)3(BTB)4 through Schiff base condensation reaction and complexation of Pd(II). Pd–MOF was found to be an effective heterogeneous catalyst for the oxidation and hydrogenation of various substrates under mild reaction conditions. This catalytic method is highly active and shape selective. Graphical...
This paper focuses on the catalysis of the hydroformylation of aliphatic olefins and aromatic olefins using the multi-faceted cobalt–rhodium heterobimetallic nanoparticle (Co2Rh2). The Co2Rh2 nanocatalyst retained its catalytic activity, allowing for 5 cycles through the reaction.
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