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A range of bio‐based rubbery thermosets have been synthesized by the cationic copolymerization of conjugated soybean oil, styrene, and 1,5‐hexadiene or isoprene as flexible crosslinkers. The thermal, and mechanical properties, as well as the wear behavior, of these new bio‐rubbers are reported. The amount of styrene and the type of diene incorporated have the greatest influence on the properties of...
A range of thermoset plastics have been prepared by the cationic copolymerization of olive, peanut, sesame, canola, corn, soybean, grapeseed, sunflower, low saturation soy, safflower, walnut, and linseed oils with divinylbenzene or a combination of styrene and divinylbenzene comonomers catalyzed by boron trifluoride diethyl etherate. The chemical, physical, thermal, and mechanical properties of these...
New polymeric materials have been prepared from the cationic copolymerization of fish oil ethyl ester (NFO), conjugated fish oil ethyl ester (CFO) or triglyceride fish oil (TFO) with styrene and divinylbenzene initiated by boron trifluoride diethyl etherate (BF 3 .OEt 2 ). These materials are typical thermosetting polymers with crosslink densities ranging from 1.1x10 2 to 2...
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