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Rate constants of Claisen rearrangement of allyl phenyl ether in subcritical water (272–306°C) at 25.4MPa were determined. The activation energy in this temperature range was evaluated to be 106±5kJmol −1 . To study the kinetics of reactions occurring in water at pressures up to 40MPa and temperatures up to 400°C, we developed a flow-through high-temperature and high-pressure NMR probe equipped...
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