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Our previous rapid-scanning stopped-flow studies of the reaction of substrate-free cytochrome P450cam with peracids [T. Spolitak, J.H. Dawson, D.P. Ballou, J. Biol. Chem. 280 (2005) 20300–20309; J. Inorg. Biochem. 100 (2006) 2034–2044; J. Biol. Inorg. Chem. 13 (2008) 599–611] spectrally characterized compound I (ferryl iron plus a porphyrin π-cation radical (Fe IV O/Por + )), Cpd ES,...
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