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Temperature has an important effect on the dissociative adsorption of molecular oxygen on platinum surfaces. Here, we show that if the substrate temperature is increased to 400–600 K, the total amount of oxygen loaded onto Pt(111) can be more than twice the well-established maximum coverage of 0.25 ML. While low energy electron diffraction and STM reveal a conventional p(2 × 2) structure of the topmost...
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