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Breite Anwendbarkeit und gute Toleranz: Eine effiziente Kreuzkupplung von Aryltrimethylammoniumiodid‐Salzen mit Aryl‐, Methyl‐ und Benzylzinkchloriden ließ sich mit [Ni(PCy3)2Cl2] als Katalysator verwirklichen (siehe Schema). Die Reaktion verläuft über die Spaltung einer C‐N‐Bindung, kann auf eine Vielzahl an Substraten angewendet werden und toleriert eine Reihe funktioneller Gruppen. NMP=N‐Methylpyrrolidin.
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