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Eingeschlossen: Langsames Kristallisieren von Na[C5(CN)5], dem nichtsolvatisierten Natriumsalz von Pentacyanocyclopentadienid, ist das erste Beispiel für ein anionisches Koordinationsnetzwerk, das auf Metall‐Fulleren‐Einheiten basiert. Seine Struktur ist verwandt mit der des Typ‐I‐Gasclathrats (siehe Bild), in der ungefähr 66 % des Volumens der Elementarzelle mit Lösungsmittelmolekülen besetzt sind.
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