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The polarized Raman spectra of oriented single crystals as well as far and mid infrared spectra of pellets of RuCp 2 * (Cp* = η 5 -C 5 Me 5 ) (1) were recorded. Assuming local C 5v symmetry for the intra-ligand vibrations, pairs of Raman and IR bands of nearly equal energy result for the symmetric and antisymmetric modes, respectively, for the irreducible representations...
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