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In this work, by combining the superiority of polyoxometalates (POMs) and catalytic single‐metal site Co of metalloporphyrin, a series of mixed‐valence POM‐based metal‐organic frameworks (MOFs) composites is synthesized by a post‐modification method. The electron‐transfer property of POM@PCN‐222(Co) composite is significantly enhanced owing to the directional electron‐transfer from POM to single‐metal...
By combining the superiority of polyoxometalate (POM) and single‐metal site Co in porphyrin, a POM‐based metal–organic framework composite has been constructed by Wen‐Wen He, Ya‐Qian Lan, Shengqian Ma, and co‐workers (article number 2100762). Directional electron transfer from POM to the single‐metal site Co in PCN‐222(Co) accelerates electron‐transfer efficiency thereby affording high electrocatalytic...
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