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A zwitterionic amine bridged bis(phenolate) ytterbium(III) complex was synthesized, and its reactivity with a zinc cluster was explored. The reaction of (C 5 H 5 ) 3 Yb(THF) with the amine bridged bis(phenol) HONNOH [ONNO=Me 2 NCH 2 CH 2 N{CH 2 -(2-O-C 6 H 2 -Bu t2 -3,5)} 2 ] in a 1:2M ratio in toluene at...
Yttrium complexes stabilized by a diaminobis(phenolate) ligand were synthesized and their catalytic behavior was explored. Reaction of YCl3 with 1 equiv of LNa2 [L= Me2NCH2CH2N{CH2-(2-O-C6H2-tBu2-3, 5)}2] gave the yttrium chloride LYCl(THF) (1) in 92% yield. Complex 1 can be used as starting material to prepare the yttrium amido derivative. Complex 1 reacted with 1 equiv of LiNPh2 in THF to afford...
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