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Reaction of formamide with Ni(NO 3 ) 2 ·6H 2 O under hydrothermal condition in a mixture of MeOH/H 2 O forms a two-dimensional formate bridged sheet Ni(HCOO) 2 (MeOH) 2 (1). X-ray structure analysis reveals the conversion of formamide to formate which acts as a bridging ligand in complex 1 where the axial sites of Ni(II) are occupied by methanol used...
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