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The reactions of laser‐ablated Au, Ag, and Cu atoms with F2 in excess argon and neon gave new absorptions in the MF stretching region of their IR spectra, which were assigned to metal‐fluoride species. For gold, a NgAuF bond was identified in mixed neon/argon samples. However, this bonding was much weaker with AgF and CuF. Molecules MF2 and MF3 (M=Au, Ag, Cu) were identified from the isotopic distribution...
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