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We prepared the C 2 -symmetrical hemin, 1,2,3,4-tetraethyl-5,8-dimethyl-6,7-dipropionate porphyrin iron complex (1), and its derivatives 2-4 conjugated with glycine, valine or phenylalanine at the terminal of one of two peripheral propionates through amide linkage. These hemins were incorporated into apomyoglobin from horse heart and the reconstituted proteins were characterized by 1...
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