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A comparative investigation of seven ferrocene-containing chalcones (Fc–CO–CHCH–C 6 H 4 R, with R=OCH 3 , CH 3 , Ph, t Bu, H, Br and CF 3 ) has been performed based on their electrochemical and spectroscopical behavior as well as with DFT calculations. These compounds were prepared by Claisen-Schmidt condensation of acetylferrocene and the appropriate...
The kinetics of oxidative addition of CH 3 I to [Rh(FcCOCHCOCF 3 )(CO)(PPh 3 )], where Fc=ferrocenyl and (FcCOCHCOCF 3 ) − =fctfa=ferrocenoylacetonato, have been studied utilizing UV/Vis, IR, 1 H and 31 P NMR techniques. Three definite sets of reactions involving isomers of at least two distinctly different classes of Rh III -alkyl and...
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