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Five new complexes of copper(II) having the general formula [CuL(OAc)], where HL and OAc − represent the N,N,O-donor 4-R-2-[(2-pyridin-2-yl-ethylimino)-methyl]-phenol (R=H, Br, NO 2 and OMe) or 5-methoxy-2-[(2-pyridin-2-yl-ethylimino)-methyl]-phenol and acetate, respectively have been reported. The complexes have been synthesized in 52–80% yields by reacting one mole equivalent each...
The reactions of one equivalent each of [VO(acac) 2 ] and N-(2-pyridyl)-N′-(5-R-salicylidene)hydrazines (HphsalR) (derived from 2-hydrazinopyridine and 5-substituted salicylaldehydes) in boiling acetonitrile under aerobic conditions provide ternary complexes of oxovanadium(IV) having the general formula [VO(phsalR)(acac)]. The complexes have been characterized by analytical, magnetic and spectroscopic...
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