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Methylzinc tetrahydroborate vapour, as shown by its mass and infrared spectra, consists of an equilibrium mixture of monomeric and dimeric species; the proportion of the dimer increases as the temperature is raised from 243 to 268 K (at pressures < 10 -1 Torr). Consistent with the results of Density Functional Theory (DFT) calculations, the pattern of infrared bands of the matrix-isolated...
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