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The preparation of spherical core–shell nanoparticles formed by a gold core and an ultrathin layer of a spin crossover coordination polymer (4 nm thick) is described by Marc Coronado‐Puchau, Mónica Giménez‐Marqués, Eugenio Coronado, and co‐workers in article number 1900039. The optimal deposition into an electrical device reveals high electrical responses and memory effects in the conductance upon...
A simple chemical protocol to prepare core–shell gold@spin‐crossover (Au@SCO) nanoparticles (NPs) based on the 1D spin‐crossover [Fe(Htrz)2(trz)](BF4) coordination polymer is reported. The synthesis relies on a two‐step approach consisting of a partial surface ligand substitution of the citrate‐stabilized Au NPs followed by the controlled growth of a very thin layer of the SCO polymer. As a result,...
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