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The spin transition in a square lattice nanoparticle, whose the primitive cell is constituted of 2 metallic centres, is investigated using a two-variable elastic Ising-like model solved by Monte Carlo simulations. We show that the specific lattice geometry can lead to an important surface relaxation of both the structure and the spin-state, which are analysed by mapping the local strain. The consequence...
Synthesis of the [Fe(hptrz) 3 ](OTs) 2 spin crossover nanoparticle samples was performed. Transmission electronic microscopy was used to determine the size and size distribution of the nanoparticle samples for which a size range of 35–70nm was found – depending on the composition and the stoichiometry of the reverse micelle hexane-tergitol-water system. The factors susceptible to influence...
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