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Separation is an important industrial step with critical roles in the chemical, petrochemical, pharmaceutical, and nuclear industries, as well as in many other fields. Although much progress has been made, the development of better separation technologies, especially through the discovery of high‐performance separation materials, continues to attract increasing interest due to concerns over factors...
Solvent selection! The organically templated co‐assembly between tetrahedral [B(imidazolate)4]− and [Co(ac)]+ units leads to two previously unknown zeolitic boron imidazolate frameworks with ACO and ABW topologies (denoted BIF‐22 and BIF‐23; e‐urea=ethyleneurea), respectively. BIF‐22 is chiral and shows interesting CO2 selectivity over N2 and CH4.
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