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A series of functionalised imidazolium halide salts with substituents able to form π‐bonds have been prepared and characterised. Subsequent reaction of these imidazolium halides with Ag[C(CN)3] affords imidazolium‐based ionic liquids (ILs), some of which are characterised by extensive π–π interactions between the cation and [C(CN)3] anion. The conductivities of the room temperature ILs with the [C(CN)...
Valorization of CO2, an abundant C(1) synthon, into platform chemicals is of growing interest. In this context, a key reaction is the cycloaddition of CO2 to epoxides to form carbonates (CCE). A series of organocatalysts for this reaction, based on imidazolium salts modified with a styrene functional group and a second variable functional group, were prepared and characterized. Both the ionic salts...
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