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The elusive nitryl cyanide, NCNO2, has been synthesized and characterized. It was prepared in good yield, isolated by fractional condensation, characterized by NMR and vibrational spectroscopy, and studied by theoretical calculations. Nitryl cyanide holds promise as a high energy density material (HEDM) and might also prove useful as a HEDM building block. The simplicity and inherent stability of...
Die Verbindung NCNO2 mit ultrahoher Energiedichte wurde synthetisiert und charakterisiert, wie M. Rahm, K. O. Christe et al. in ihrer Zuschrift auf S. 7013 ff. beschreiben. Die berechnete Energiefreisetzung von 2.02 kcal g−1 bei Verbrennung ist präzedenzlos und übertrifft sogar die von HN3 um 17.4 %. Die thermische Stabilität von NCNO2, die sich 100 °C annähert, ist sehr ungewöhnlich, da die Stabilität...
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