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Porphyrin and phthalocyanine complexes bearing single‐atom catalytic sites (M‐N4) have been explored as promising electrocatalysts for CO2 reduction reaction (CO2RR), whose activity can be improved by regulating the ligands and/or the metal centers. Moreover, their photosensitive features also provide the possibility for highly efficient photoelectrocatalytic CO2RR. Herein, a novel N′NN′‐pincer‐ligand...
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