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Electrochemical synthesis of hydrogen peroxide (H2O2) via two-electron pathway of oxygen reduction reaction is a promising alternative to the current anthraquinone process. The H2O2 production from O2 is a competing reaction with four-electron O2 reduction to H2O, and the selectivity is related to the adsorption energy of the OOH intermediate on electrocatalysts surface. Generally, the properties...
OH due to their limited exposed active sites and difficulty in the reduction of Fe(III) to Fe(II). Here, enhanced catalytic performance was achieved by using an iron-based metal organic framework (MIL-88B-Fe) as a heterogeneous Fenton-like catalyst over a wide pH range (4–6). The catalytic activity of MIL-88B-Fe was about 1–3 orders of magnitude higher than that of three other conventional catalysts...
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