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The kinetics of zinc electrodeposition from acid sulphate solution on a platinum electrode was investigated by means of stationary polarization curves, interfacial pH measurement and electrochemical impedance spectroscopy. The effect of pH, namely pH 2, 3 and 4, was analyzed. A significant dependence of Zn electrodeposition with solution pH was verified. The results obtained cannot be predicted by...
The electrodeposition of Zn-Ni in sulfate solutions has been investigated by means of polarization curves, morphological analysis and electrochemical impedance using a rotating disc electrode.The polarization curves showed two parts, the first one related to the Zn-Ni normal codeposition and the second one to the Zn-Ni anomalous codeposition. The mass transport influenced only the Zn-Ni normal codeposition...
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