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The mobility of phosphate groups in aqueous solutions of casein micelles and sodium caseinate from bovine milk was determined with magic angle spinning (MAS) 31P NMR as a function of the pH between pH 4 and pH 8. The chemical shifts and the relative amplitudes of the signals from mobile inorganic phosphate (orthophosphate) and mobile organic phosphate (phosphorylated serines) as well as that of immobile...
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