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The effect of orthophosphate (0–0.1 m) on the aggregation of sodium caseinate in water (10–80 g L−1) induced by calcium ions was studied using confocal microscopy, sedimentation and 31P magic angle spinning nuclear magnetic resonance spectroscopy. In the presence of calcium ions (0–0.1 m), orthophosphate binds to the caseins leading to the formation of complexes involving all four types of casein...
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