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A 71-step reaction-kinetic model for the formation of 1,3,6,8- and 1,3,7,9-tetrachlorodibenzo-p-dioxins (TCDDs) from the oxidation of 2,4,6-trichlorophenol in the presence of hexane is developed based on experimental data and a simpler model that was previously published in the literature. The rate of reaction of phenoxyl-radicals with molecular oxygen has recently been experimentally demonstrated...
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