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Fischer-Tropsch (FT) synthesis was performed over 15%Co/CeSi and 15Co/CeMnSi catalysts using a 1L CSTR at 230°C, 1.89MPa and a H2/CO ratio of 1.86. The oxygenate selectivity for both catalysts increased with increasing time-on-stream during FT synthesis. X-ray diffraction, EXAFS and HR-TEM analyses of fresh catalysts and those withdrawn during FT synthesis indicate that increases in the selectivity...
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