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The rotational barriers of the anthracenyl and triptycyl units in 1‐(9‐anthracenyl)‐1′‐(9‐triptycyl)ferrocene were independently measured as 11.6 and 17.6 kcal mol–1, respectively. Attempts to reduce 9‐ferrocenoylanthracene to 9‐(ferrocenylmethyl)anthracene, 3, in which the sandwich moiety and the planar aromatic are linked through an angular methylene unit, were thwarted by reduction of the anthracene...
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