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Given the limitations inherent in current intercalation‐based Li‐ion batteries, much research attention has focused on potential successors to Li‐ion batteries such as lithium–sulfur (Li‐S) batteries and lithium–oxygen (Li‐O2) batteries. In order to realize the potential of these batteries, the use of metallic lithium as the anode is essential. However, there are severe safety hazards associated with...
CO2‐responsive spin‐state conversion between high‐spin (HS) and low‐spin (LS) states at room temperature was achieved in a monomeric cobalt(II) complex. A neutral cobalt(II) complex, [CoII(COO‐terpy)2]⋅4 H2O (1⋅4 H2O), stably formed cavities generated via π–π stacking motifs and hydrogen bond networks, resulting in the accommodation of four water molecules. Crystalline 1⋅4 H2O transformed to solvent‐free...
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