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High‐mobility and air‐stable n‐type organic field transistors based on solution‐crystallized N,N′‐1H,1H‐perfluorobutyldicyanoperylene carboxydi‐imide (PDIF‐ CN2) are developed. Electron mobility as high as 1.3 cm2 V−1 s−1 is achieved owing to the almost‐perfect periodic crystal packing.
As reported by Antonio Facchetti, JunTakeya, and coworkers, molecules of an n‐type semiconductor PDIF‐CN2 assemble with perfect periodicity into a molecular‐crystal plate. The plate, formed in a narrow gap from a solution, works as an excellent n‐type semiconductor. It is implemented in the best‐performing printed logic element.
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