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When several diallyl esters were subjected to ADMET using Grubbs “first generation” catalyst only oligomerization occurred (DPs<7), but with allyl hex-5-enoate the product had a DP of 14, and with allyl undec-10-enoate the products usually had DPs in the range 41–79. It is suggested that with the diallyl esters an intermediate is formed in which the ester carbonyl chelates onto the metal centre...
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