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An electrochemical sensor using the composites of graphene quantum dots (GQDs) and β-cyclodextrins (β-CDs) functionalized glassy carbon electrode (GCE) was developed for determination and recognition of tyrosine (Tyr) enantiomers which are biomarker of depression. The modified electrode is simple to fabricate and rapid, sensitive, selective to detect the Tyr enantiomers. In order to further validate...
In order to assess cytotoxicity of quantum dots (QDs), new reliable analytical techniques that can provide comparative information at a single-cell level are required. In this study, a single cell ICP–MS (SC-ICP–MS) method was established to determine intracellular QDs in single cells after exposure. Uptake kinetics of QDs into cells was studied using the established method. The results were compared...
A rapid, simple and real-time colorimetric assay for detecting phosphate anions (PO 43− ) in aqueous solution was developed. The method was based on a novel functionalized gold nanoparticles (MPTP-Zn-AuNPs), which was synthesized by the ligand-exchange reaction of 4′-(4-mercaptophenyl)-2,2′:6′,2″-terpyridine zinc(II) complex (MPTP-Zn) with citrate-stabilized aqueous AuNPs. The strong...
Nitroexplosives, such as 2,4,6-trinitrotoluene (TNT) which is a leading example of nitroaromatic explosives, are causing wide concern. Motivated by the urgent demand for trace analysis of explosives, novel surface-enhanced Raman spectroscopy substrates based upon highly ordered Au nanoparticles have been fabricated by a simple droplet evaporation method. It is noteworthy that an ethylhexadecyldimethyl...
This paper reported the coupling technique of Ag island film-enhanced fluorescence with rare earth co-luminescence effect of Tb–Gd–sodium dodecyl benzene sulfonate (SDBS)–protein system. While the collagen is used as the separator between Ag island film and the fluorophore because it not only can decrease the fluorescence of the blank, but also can promote the adsorption of other proteins and change...
An electroosmotic flow (EOF)-switchable poly(dimethylsiloxane) (PDMS) microfluidic channel modified with cysteine has been developed. The native PDMS channel was coated with poly(diallyldimethylammonium chloride) (PDDA), and then gold nanoparticles by layer-by-layer technique was assembled on PDDA to immobilize cysteine. The assembly was followed by infrared spectroscopy/attenuated total reflection...
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