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Fluoride-releasing restorative materials are available for remineralization of enamel and root caries. However, remineralization of dentin is more difficult than remineralization of enamel due to the paucity of apatite seed crystallites along the lesion surface for heterogeneous crystal growth. Extracellular matrix proteins play critical roles in controlling apatite nucleation/growth in collagenous...
Phosphorous‐based templating analogs of extracellular matrix proteins are used as templates in conjunction with polycarboxylic acid‐stabilized amorphous calcium phosphate nanoprecursors to create a highly ordered intrafibrillar apatite crystallite assembly within a collagen fibril. The assembly recapitulates the gap and overlap arrangement of collagen molecules.
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