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In this work, amorphous poly(ε-caprolactone-co-δ-valerolactone) (P[CL-co-VL]) random aliphatic copolyesters were synthesized and investigated as biodegradable impact modifiers for PLA in order to enhance the low brittleness of renewable and biodegradable polylactide (PLA). The random copolyesters were produced by ring-opening polymerization between δ-valerolactone (VL) and ε-caprolactone (CL) in bulk...
This paper is the first report about the morphology of semi-crystalline poly(ε-caprolactone) (PCL) brushes studied by Atomic Force Microscopy (AFM) in tapping mode. This represents a convenient way to observe how the growth of a polymer proceeds from a thiol monolayer on gold substrate in terms of grafting density and thiol monolayer stability. The synthesis of semi-crystalline PCL brushes was carried...
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