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Higher alcohol synthesis from syngas is studied over K/MoS2 domains supported on mesoporous carbon (C), mixed MgAl oxide (MMO), or mixtures thereof. While the carbon support offers high ethanol productivity, the MMO support yields enhanced C3+OH selectivity. MoKMMO-C, whereby Mo is initially contained on MMO then ground with carbon, behaves similar to the parent MoKMMO catalyst, as Mo on MMO has limited...
Potassium promoted molybdenum sulfide catalysts are well-known for the conversion of synthesis gas (H2 and CO) to higher alcohols, primarily ethanol and propanol. Basic supports composed of mixed MgAl based oxides from decomposed hydrotalcites are known to yield enhanced higher alcohol selectivities compared to bulk or carbon supported molybdenum sulfide catalysts. In this study, the role of the metal...
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