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Potassium promoted molybdenum sulfide catalysts are well-known for the conversion of synthesis gas (H2 and CO) to higher alcohols, primarily ethanol and propanol. Basic supports composed of mixed MgAl based oxides from decomposed hydrotalcites are known to yield enhanced higher alcohol selectivities compared to bulk or carbon supported molybdenum sulfide catalysts. In this study, the role of the metal...
The influence of Co addition on the activity and selectivity of Rb-promoted Mo2C/α-Al2O3 catalysts in CO hydrogenation was explored. The reaction was performed in a fixed-bed reactor system operating at 573 K, 30 bar, and CO/H2 ratio of 1. Addition of Co enhanced the production rates of hydrocarbons and higher alcohols over Rb-promoted Mo2C/α-Al2O3 by about 60 % without significantly increasing the...
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