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Lipoic acid is a sulfur-containing 8-carbon fatty acid that functions as a central cofactor in multienzyme complexes that are involved in the oxidative decarboxylation of glycine and several α-keto acids. In its functional form, it is bound covalently in an amide linkage to the ε-amino group of a conserved lysine residue of the “lipoyl bearing subunit,” resulting in a long “swinging arm” that shuttles...
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