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Photoresponsive metal–organic frameworks (PMOFs) are of interest for tailorable CO2 adsorption. However, modulation of CO2 adsorption on PMOFs is based on steric hindrance or structural change owing to weak interactions between CO2 and active sites. It is challenging to fabricate PMOFs with strong but tailorable sites for CO2 adsorption. Now, the construction of PMOFs with target‐specific (strong)...
“Smarte” Adsorbentien mit targetspezifischen aktiven Zentren für den selektiven CO2‐Abfang werden von X.‐Q. Liu, L.‐B. Sun et al. in ihrer Zuschrift auf S. 6672 beschrieben. Amine wurden als aktive Zentren in photoresponsive Metall‐organische Gerüste (PMOFs) eingeführt. Die durch UV/Vis‐Bestrahlung ausgelöste cis/trans‐Isomerisierung von Azobenzolmotiven führt zur Exposition/Abschirmung der Amine...
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