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Electrocatalytic water oxidation using the oxidatively robust 2,7‐[bis(2‐pyridylmethyl)aminomethyl]‐1,8‐naphthyridine ligand (BPMAN)‐based dinuclear copper(II) complex, [Cu2(BPMAN)(μ‐OH)]3+, has been investigated. This catalyst exhibits high reactivity and stability towards water oxidation in neutral aqueous solutions. DFT calculations suggest that the OO bond formation takes place by an intramolecular...
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