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Molecular modeling (GEMM 7.3) and molecular mechanics calculations (YETI V 5.3) using the X-ray coordinates for acetylcholinesterase (AChE) from Torpedo californica indicate electrostatic stabilization by the active site. Glu-199, of the developing positive charge on the incipient carbonium ion in the dealkylation in the adducts of AChE with P S C R and PsCs diastereomers of 2-(3,3-dimethylbutyl)...
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