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The 5α-reduction of testosterone in target tissues is a key step in androgen physiology; however, 5α-reduced C 19 steroids are sometimes synthesized in testis via a pathway that does not involve testosterone as an intermediate. We studied the metabolism of 5α-reduced C 21 steroids by human cytochrome P450c17 (hCYP17), the enzyme responsible for conversion of C 21...
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