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A highly porous metal‐organic framework (MOF) incorporating two kinds of second building units (SBUs), i.e., dimeric paddlewheel (Zn2(COO)4) and tetrameric (Zn4(O)(CO2)6), is successfully assembled by the reaction of a tricarboxylate ligand with ZnII ion. Subsequently, single‐crystal‐to‐single‐crystal metal cation exchange using the constructed MOF is investigated, and the results show that CuII and...
On page 2334, R. Q. Zou, Y. L. Zhao, and co‐workers present a porous metal‐organic framework (MOF) that serves as a platform for studying the metal exchange effect on both CO2 adsorption and catalytic fixation. The effect is demonstrated by catalytic CO2 cycloaddition with propylene oxide to produce propylene carbonate. Molecular dynamic simulations are carried out to further confirm the catalytic...
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