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Polyfluorene is selective for semiconducting SWCNTs when the starting ratio of metallic:semiconducting is below 67 : 33, whereas with higher ratios the amount of metallic SWCNTs dispersed dramatically increases. For more information, see the Full Paper by A. Adronov et al. on page 9799 ff.
Applications of single‐walled carbon nanotubes (SWCNTs) are hampered by the mixtures of metallic and semiconducting SWCNTs that are present in commercial samples. Separation of SWCNTs according to electronic type is therefore extremely important. Recently, the selective interaction between the conjugated polymer, poly(9,9‐di‐n‐dodecyl‐fluorenyl‐2,7‐diyl) and semiconducting SWCNTs has been reported...
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