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A series of nanoporous frameworks constructed by a polycatenated isoreticular 1D ribbon of rings have been developed. The orientation of catenated ribbons can be fine tuned by varying counter anions, which allows both pore size and shape to be systematically adjusted in a pre‐synthetic process. Distinct from conventional pore construction modes in which the organic linkers are alternately connected...
A series of nanoporous frameworks with tunable pore metrics and functions has been prepared using a polycatenation approach. As described in the Full Paper by J. Zhang et al. on p. 2488 ff., these unique porous structures can interconvert through an anion‐exchange process and can be post‐synthetically photomodified, which resulted in a significant effect on the adsorption properties.
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