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We report here the development of a suite of biocompatible SuFEx transformations from the SOF4‐derived iminosulfur oxydifluoride hub in aqueous buffer conditions. These biocompatible SuFEx reactions of iminosulfur oxydifluorides (R‐N=SOF2) with primary amines give sulfamides (8 examples, up to 98 %), while the reaction with secondary amines furnish sulfuramidimidoyl fluoride products (8 examples,...
SuFEx wird biologisch: Biokompatible SOF4‐basierte SuFEx‐Reaktionen, die bei niedriger Konzentration in wässriger Lösung unter milden pH‐ und Temperaturbedingungen ablaufen, bieten Zugang zu asymmetrischen und am Schwefel(VI)‐Zentrum trisubstituierten Produkten mit vielseitiger S‐N‐ und S‐O‐Konnektivität. Die SuFEx‐Biokonjugation von Iminosulfuroxydifluoriden mit BSA‐Protein oder einzelsträngiger...
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