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Hydroxyl end-capped telechelic polymers with poly(methyl methacrylate)-block-poly(n-butyl acrylate) (PMMA-b-PBA) backbones have been prepared via atom transfer radical polymerisation (ATRP) together with a nucleophilic substitution reaction. A hydroxyl-functionalised PMMA macroinitiator (HO-PMMA-Br) was prepared via ATRP at the optimised reaction temperature (60 °C) using 2-hydroxyethyl 2-bromoisobutyrate...
Poly(N-acetylethylenimine) was found to form a crystalline inclusion complex with γ-cyclodextrin (CD). It did not form crystalline inclusion complexes with α-CD or β-CD. It is a hydrophilic, nitrogen atom-containing polymer that forms a crystalline inclusion complex with CD. FT-IR spectroscopy, thermogravimetry analysis, X-ray diffraction, 1 H NMR spectra and 13 C CP/MAS NMR spectra...
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