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The new mixed metal carbide containing cluster compounds PtFe4(CO)12(COD)(μ5-C) 1 and PtFe4(CO)12(PMe2Ph)2(μ5-C), 2 were obtained by metal–metal exchange reactions between [Et4N]2[Fe5(C)(CO)14] with Pt(COD)Cl2 in the presence of TIPF6 and Pt(PMe2Ph)2Cl2, respectively. Compound 1 was also obtained by the reaction of Fe5(CO)15(μ5-C) with Pt(COD)2 in the presence of UV irradiation but in a lower yield...
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