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Nucleophilic substitutions, including SN1 and SN2, are classical and reliable reactions, but a serious drawback is their intolerance for both bulky nucleophiles and chiral tertiary alkyl electrophiles for the synthesis of a chiral quaternary carbon center. An SRN1 reaction via a radical species is another conventional method used to carry out substitution reactions of bulky nucleophiles and alkyl...
Eine stereospezifische nukleophile Substitution zwischen tertiären Alkylbromiden und tertiären Alkylalkoholen wird auf S. 4375 im Forschungsartikel von Toshiki Nokami, Takashi Koike, Manabu Abe, Eiji Shirakawa, Takashi Nishikata und Mitarbeitern beschrieben. Der eintretende Alkohol greift formal die C‐Br‐Bindung an, um eine retentive Substitution unter Bildung von tertiären Alkylethern einzugehen...
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