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In this study, ZnO thin films have been electrodeposited from zinc nitrate solution without using any catalyst, additive, or seed layer on two kinds of substrates (Si and ITO glass). Using cyclic voltammetry and chronoamperometry, it was shown that the mechanism of ZnO deposition strongly depends on the substrate used and its overpotential for nitrate reduction. On Si, the nitrate reduction into nitrite...
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